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Extent

1 digital object.

Cite This Work

Peltier, Jesse L.; Martin, David; Soleilhavoup, Michele; Jazzar, Rodolphe; Bertrand, Guy (2020). Data from: Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. UC San Diego Library Digital Collections. https://doi.org/10.6075/J0T15256

Description

The precise preparation of monodisperse nanomaterials is among the most fundamental tasks in inorganic synthesis and materials science. Achieving this goal by galvanic exchange is hardly predictable, and often results in major structural changes and polydisperse mixtures. Taking advantage of the enhanced stability imparted by ambiphilic carbenes, we report and rationalize the absolute templating—the complete exchange of metals in a template—of group 11 clusters across the entire coinage metal family by means of galvanic exchange. We further delineate that these species provide a molecular model for better understanding the reduction of CO₂ at M(111) coinage metal surfaces.

Creation Date

• 2019 to 2020

Date Issued

• 2020

Authors

• Martin, David
• Peltier, Jesse L.
• Soleilhavoup, Michele

Principal Investigator

• Bertrand, Guy

Co Principal Investigator

• Jazzar, Rodolphe

Funding

This work was supported by the U.S. Department of Energy, Office of Science, Basic Energy Sciences, Catalysis Science Program, under Award No. DE-SC0009376. J.L.P. was financially supported by the National Science Foundation (NSF) with a Graduate Research Fellowship (DGE-1650112) and the Tribal Membership Initiative Fellowship administered by the UC San Diego Graduate Division. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation. We also acknowledge the Keck Foundation for providing computational resources.

Topics

• Carbenes
• Coinage metal cluster
• Copper cluster
• Cyclic(alkyl)(amino)carbenes (CAACs)
• Density Functional Theory (DFT)
• Galvanic exchange
• Gold cluster
• Nanoclusters
• Silver cluster
• Trinuclear cluster

Formats

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• data
• text

Language

• No linguistic content; Not applicable

Identifier

Identifier: David Martin: https://orcid.org/0000-0002-3257-9876

Identifier: Guy Bertrand: https://orcid.org/0000-0003-2623-2363

Identifier: Jesse L. Peltier: https://orcid.org/0000-0002-3493-2127

Identifier: Michele Soleilhavoup: https://orcid.org/0000-0001-5339-921X

Identifier: Rodolphe Jazzar: https://orcid.org/0000-0002-4156-7826

Related Resource

Primary associated publication

• Peltier, Jesse L.; Martin, David; Soleilhavoup, Michele; Jazzar, Rodolphe; Bertrand, Guy (2020). Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. J. Am. Chem. Soc. https://doi.org/10.1021/jacs.0c07990