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Measurements of Generated and Ambient Marine Aerosol Particles in May and June 2010 on board the R/V Atlantis during the California Nexus (CalNex) Experiment

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1 digital object.

Cite This Work

Frossard, Amanda A.; Russell, Lynn M.; Maben, John R.; Long, Michael S.; Keene, William C.; Reid, Jeffrey S.; Kinsey, Joanna; Kieber, David J.; Quinn, Patricia K.; Bates, Timothy S. (2017). Measurements of Generated and Ambient Marine Aerosol Particles in May and June 2010 on board the R/V Atlantis during the California Nexus (CalNex) Experiment. UC San Diego Library Digital Collections. https://doi.org/10.6075/J00P0WX6

Date Collected

2010-05-14 to 2010-06-08

Date Issued

2017

Principal Investigators

Researchers

Methods

Measurements of ambient and generated primary marine aerosol particles were collected on board the R/V Atlantis off the coast of California in the eastern Pacific Ocean from 14 May to 7 June 2010.

Generated primary marine aerosol particles (gPMA) were produced with two model ocean systems, the Bubbler and the Sea Sweep.

Sea Sweep Description:
The Sea Sweep consisted of a raft deployed over the side of the ship in the ambient seawater. Bubbles were created with stainless-steel diffusion frits at 75 cm below the ocean surface, and the resulting aerosol particles were transported onto the ship for characterization.

Bubbler Description:
Model primary marine aerosol (gPMA) was produced in a high-capacity generator fabricated from Pyrex and Teflon (referred to here as the Bubbler). See Keene et al. [2007] for a detailed description and schematic of the device and Long et al. [2014] for an explanation of modifications implemented for deployment on ships at sea. Briefly, the 20-cm-diameter generator consisted of a 122-cm-deep seawater reservoir underlying a 97-cm-deep atmosphere. Fresh seawater drawn from approximately 5-m depth through the ship’s clean seawater line flowed into the base of the seawater reservoir (typically at 4 L min^-1) and drained evenly over the top annular rim thereby continuously replacing the seawater surface and minimizing formation of standing bubble rafts. Bubbles were generated by two mechanisms. First, bubble plumes were produced by pumping ultra-pure air through a coarse porosity sintered glass frit (45-mm diameter, 145- to 174-μm pore size) or through 11 fine porosity sintered glass frits (90-mm diameter, 10- to 20-μm pore size) positioned at an average depth of 84 cm below the air-seawater interface, which is within the range of ambient bubble-cloud depths generated by breaking waves on the open-ocean surface. The fine frits were plumbed as two independently regulated sets of 5 and 6 frits each that were positioned at average depths of approximately 60 and 100 cm, respectively. To prevent flooding via backflow of seawater into the bubble-air feed lines, it was necessary to maintain finite positive pressure behind and associated minimal air flow of 0.2 L min^-1 through the course frit and each set of fine frits (total of 0.6 L min^-1). Second, bubble plumes were also produced by one or two seawater jets at combined flow rates of 1 to 4 L min^-1 that impinged on the air-seawater interface. Jet nozzles were 0.32-cm ID and positioned at 50 cm above the interface.

gPMA were emitted to the headspace of the Bubbler when bubbles rose to and burst at the air-seawater interface. Ultra-pure sweep air flowed through the headspace above the seawater reservoir at 48 to 70 L min^-1 (depending on the combined flow rates required to accommodate different sampling devices). During most sampling periods, sweep air was hydrated to a relative humidity (RH) of 80±2%. The generator (Bubbler) was blank tested by measuring mPMA number concentrations in the headspace at typical flow rates of bubble and sweep air but with no seawater in the reservoir. All blank tests yielded undetectable particle number concentrations (less than 2 cm^-3) indicating that all particles measured during routine operation originated from seawater.

Particle Number Size Distributions:
Number size distributions were measured under different configurations of the system. For some characterizations, a diffusion dryer was mounted in line between the generator and the sizing instruments and, for others, no dryer was mounted in line. In addition, for some characterizations, the scanning electrical mobility spectrometer (SEMS, Brechtel Manufacturing, Inc.) was plumbed to use dry room air as sheath air and, for others, humid sample air was used as sheath air. Finally, for some characterizations, the aerodynamic particle sizer (APS, TSI) was configured with the standard brass inlet and, for others, it was configured with a custom plastic inlet, which helped minimize changes in the temperature and relative humidity of the sample air stream. The combined particle sizes measured ranged from 0.01 to 15 µm in diameter.

Particle Filter Sampling:
Ambient atmospheric submicron particles were dried using a temperature and humidity controlled inlet that faced into the wind and were sampled on 37 mm Teflon filters. Submicron gPMA from the Sea Sweep dried with a temperature and humidity controlled inlet and bulk, un-dried gPMA from the Bubbler were collected on 37 mm Teflon filters. These samples were frozen and transported to the laboratory for analysis by Fourier transform infrared (FTIR, Bruker Tensor 27) spectroscopy in a temperature and humidity controlled clean room. The gPMA samples were dehydrated prior to final analysis. The FTIR spectrum for each filter was analyzed with an automated algorithm that baselined the spectra. Absorptivity and molar masses were used to convert peak area at specific wavenumbers to mass for the organic functional groups hydroxyl, alkane, amine, carboxylic acid, and carbonyl. The total organic mass (OM) is calculated as the sum of the concentrations of the organic functional groups.

Size-resolved gPMA was sampled from the generator’s head space at 30 L min^-1 with two non-rotating Multi-Orifice Uniform Deposit Impactors (MOUDIs, [Marple et al., 1991]) operated in parallel. Substrates and back filters from one impactor were analyzed for major ions and those for the other impactor were analyzed for water extractable organic carbon (OCwe). The aerodynamic cut diameters for the impactor’s size fractions were 18, 10, 5.6, 3.2, 1.8, 1.0, 0.56, 0.32, and 0.18 µm. Impactors for analysis of ionic constituents were configured with 47-mm diameter polycarbonate substrates (Whatman 111107) and 37-mm diameter quartz backup filters. Impactors for analysis of OCwe were configured with pre-combusted 47-mm diameter aluminum substrates and 37-mm diameter quartz backup filters.

After recovery, samples for analysis of major ions were transferred to precleaned 10-ml HDPE tubes, stored frozen, subsequently extracted in 5 mL deionized water (DIW), and analyzed by high-performance ion chromatography (IC) at the University of Virginia (UVA). Samples for analysis of OCwe were transferred to precombusted 10-mL Pyrex centrifuge tubes, extracted immediately after recovery in 5 mL DIW, stored frozen, and analyzed with a Shimadzu Model TOC-V CSH carbon analyzer at the State University of New York (SUNY). Data for gPMA samples were corrected based on median concentrations of analytes measured in dynamic handling blanks (5 impactors each for major ions and OCwe) that were loaded and unloaded during the campaign and subsequently processed and analyzed using procedures identical to those used for samples.

Seawater Sampling:
Seawater was sampled at the inlet to the generator. Unfiltered seawater for analysis of major ions was sampled in precleaned 10-ml HDPE tubes, stored frozen, and analyzed by IC at UVA. Seawater for analysis of dissolved organic carbon (DOC) was filtered through 0.2 μm Whatman POLYCAP 75 AS cartridge into precombusted 10-mL Pyrex centrifuge tubes, stored frozen, and analyzed with a Shimadzu Model TOC-V CSH carbon analyzer at SUNY.

Other:
Size distributions of bubbles produced in the Bubbler were determined using computer enhanced camera images taken 2 to 4 cm below the model ocean surface.

Funding

National Science Foundation grants OCE-0948420, OCE-1129836, OCE-0948216, OCE-1129896, OCE-1129580, AGS-1252755

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Referenced by

Frossard, A.A. and L.M. Russell (2012), Removal of Sea Salt Hydrate Water from Seawater-Derived Samples by Dehydration, ES&T. 46, 13326-13333. https://doi.org/10.1021/es3032083

Frossard, A.A., L.M. Russell, S.M. Burrows, S.M. Elliott, T.S. Bates, P.K. Quinn (2014a), Sources and Composition of Submicron Organic Mass in Marine Aerosol Particles, JGR. https://doi.org/10.1002/2014JD021913

Keene WC, Long MS, Reid JS, Frossard AA, Kieber DJ, Maben JR, Russell LM, Kinsey JD, Quinn PK, Bates TS. 2017. Factors That Modulate Properties of Primary Marine Aerosol Generated From Ambient Seawater on Ships at Sea. Journal of Geophysical Research-Atmospheres. 122(21):11961-11990. https://doi.org/10.1002/2017jd026872

Kieber, D. J., W. C. Keene, A. A. Frossard, M. S. Long, L. M. Russell, J. R. Maben, J. D. Kinsey, I. M. B. Tyssebotn, P. K. Quinn, and T. S. Bates (2016), Coupled ocean-atmosphere loss of marine refractory dissolved organic carbon, Geophys. Res. Lett., 43. https://doi.org/10.1002/2016GL068273

Long, M. S., W. C. Keene, D. J. Kieber, A. A. Frossard, L. M. Russell, J. R. Maben, J. D. Kinsey, P. K. Quinn, and T. S. Bates (2014), Light-enhanced primary marine aerosol production from biologically productive seawater, Geophys. Res. Lett., 41, 2661–2670. https://doi.org/10.1002/2014GL059436

Quinn, P. K., T. S. Bates, K. S. Schulz, D. C. Coffman, A. A. Frossard, L. M. Russell, W. C. Keene, and D. J. Kieber (2014), Contribution of sea surface carbon pool to organic matter enrichment in nascent sea spay aerosol, Nature Geosci., 7, 228-232. https://doi.org/10.1038/NGEO2092

Measurements of Generated and Ambient Marine Aerosol Particles in May and June 2010 on board the R/V Atlantis during the C...

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